Acta Metallurgica Sinica (English Letters) ›› 2021, Vol. 34 ›› Issue (11): 1601-1608.DOI: 10.1007/s40195-021-01288-0
Special Issue: 2020-2021高熵合金; 2021年腐蚀专辑
Ben-Qi Xu1,2, Hui Zhang1,2(
), Dong Ma2, Qun-Shuang Ma2, Li-Zhai Pei2
Received:2021-05-12
Revised:2021-06-24
Accepted:2021-06-28
Online:2021-11-10
Published:2021-07-20
Contact:
Hui Zhang
About author:Hui Zhang huizhang@ahut.edu.cnBen-Qi Xu, Hui Zhang, Dong Ma, Qun-Shuang Ma, Li-Zhai Pei. Ageing Hardening Mechanism and Corrosion Resistance in the Fe65Cr13Cu3(CoMnMoNiAlTi)19 Medium-Entropy Stainless Alloy[J]. Acta Metallurgica Sinica (English Letters), 2021, 34(11): 1601-1608.
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Fig. 3 TEM images of the solidified ME-SA: a, b bright field images, c, d diffraction patterns of the particles and schematic diagram. The red solid circle represents BCC and B2. The yellow dot only represents B2
| State | Regions | Fe | Cr | Ni | Co | Mo | Mn | Al | Ti | Cu |
|---|---|---|---|---|---|---|---|---|---|---|
| As-solidified | Matrix | 64.8 | 15.1 | 2.4 | 6.1 | 2.9 | 1.8 | 2 | 3.1 | 1.8 |
| Particles | 53.2 | 12.7 | 5.7 | 7.1 | 2.7 | 3.4 | 5.1 | 5.7 | 4.4 | |
| As-aged | Matrix | 63.1 | 15.6 | 2.4 | 6.0 | 3.2 | 2.8 | 2.4 | 3.0 | 1.5 |
| Particles | 16.1 | 1.8 | 19.8 | 13.4 | 1.1 | 2.4 | 19.4 | 22.6 | 3.4 |
Table 1 Compositions of the precipitates and matrix in the solidified and aged ME-SA by TEM-EDS (at.%)
| State | Regions | Fe | Cr | Ni | Co | Mo | Mn | Al | Ti | Cu |
|---|---|---|---|---|---|---|---|---|---|---|
| As-solidified | Matrix | 64.8 | 15.1 | 2.4 | 6.1 | 2.9 | 1.8 | 2 | 3.1 | 1.8 |
| Particles | 53.2 | 12.7 | 5.7 | 7.1 | 2.7 | 3.4 | 5.1 | 5.7 | 4.4 | |
| As-aged | Matrix | 63.1 | 15.6 | 2.4 | 6.0 | 3.2 | 2.8 | 2.4 | 3.0 | 1.5 |
| Particles | 16.1 | 1.8 | 19.8 | 13.4 | 1.1 | 2.4 | 19.4 | 22.6 | 3.4 |
Fig. 4 TEM images of the ME-SA after ageing at 500 °C: a, b bright field images, c, d diffraction patterns of the particles and schematic diagram. The red solid circle represents the disordered BCC structure B2 and D03. The yellow dashed circle represents B2 and D03, and the blue dotted circle represents only D03
Fig. 5 a Microhardness evolution of the alloys after ageing at 440-530 °C; b compressive engineering stress-strain curves of the alloys after ageing at 500 °C
| Samples | Ecorr (VSCE) | icorr (μA cm-2) | Eop (VSCE) | ip (μA cm-2) | icrit (μA cm-2) |
|---|---|---|---|---|---|
| ME-SA | -0.385 | 63.09 | 0.96 ± 0.02 | 223.9 ± 0.5 | 251.2 ± 0.5 |
| 17-4 PH | -0.442 | 354.81 | 0.97 ± 0.02 | 225.7 ± 0.5 | 944.1 ± 0.5 |
Table 2 Fitting electrochemical parameters of the ME-SA and 17-4 PH alloys
| Samples | Ecorr (VSCE) | icorr (μA cm-2) | Eop (VSCE) | ip (μA cm-2) | icrit (μA cm-2) |
|---|---|---|---|---|---|
| ME-SA | -0.385 | 63.09 | 0.96 ± 0.02 | 223.9 ± 0.5 | 251.2 ± 0.5 |
| 17-4 PH | -0.442 | 354.81 | 0.97 ± 0.02 | 225.7 ± 0.5 | 944.1 ± 0.5 |
Fig. 8 XPS spectra of the passive films formed on the ME-SA after passivation for 1 h at + 0.4 VSCE in 15 wt% H2SO4 solution at room temperature: a Cr 2p3/2; b Fe 2p3/2; c Al 2p; d Ti 2p 3/2; e Mo 3d; f Co 2p3/2; g Cu 2p3/2; h Mn 2p3/2; i Ni 2p3/2; j O 1 s; k cationic fractions in the passive film
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