Acta Metallurgica Sinica (English Letters) ›› 2024, Vol. 37 ›› Issue (3): 525-536.DOI: 10.1007/s40195-024-01680-6
Special Issue: 2024年镁合金专辑; 2024年 腐蚀专辑; 2024年 复合材料专辑
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Liwen Chen1, Jianhui Jing1, Lulu Zhang1, Jing Li2, Weipeng Chen1, Limin Li1, Yuan Zhao1, Hua Hou1,3, Yuhong Zhao1,4,5(
)
Received:2023-11-01
Revised:2023-12-20
Accepted:2024-01-09
Online:2024-03-10
Published:2024-03-27
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Yuhong Zhao, Liwen Chen, Jianhui Jing, Lulu Zhang, Jing Li, Weipeng Chen, Limin Li, Yuan Zhao, Hua Hou, Yuhong Zhao. Corrosion Behavior of Graphene Nanosheets Reinforced Magnesium Matrix Composites in Simulated Body Fluids[J]. Acta Metallurgica Sinica (English Letters), 2024, 37(3): 525-536.
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| Mg | Al | Zn | Mn | Si | Fe | Cu | Ni |
|---|---|---|---|---|---|---|---|
| Bal. | 8.30 | 0.54 | 0.23 | 0.04 | 0.02 | 0.04 | 0.04 |
Table 1 Chemical composition of AZ91D Mg alloy (mass fraction, %)
| Mg | Al | Zn | Mn | Si | Fe | Cu | Ni |
|---|---|---|---|---|---|---|---|
| Bal. | 8.30 | 0.54 | 0.23 | 0.04 | 0.02 | 0.04 | 0.04 |
| Number | c (%) | T (℃) | R (r/min) | V (m/s) | F (kN) | G (MPa) |
|---|---|---|---|---|---|---|
| No. 1 | 0.0 | 610 | 140 | 2.0 | 2160 | 102 |
| No. 2 | 0.3 | 610 | 140 | 2.0 | 2160 | 102 |
| No. 3 | 0.6 | 610 | 140 | 2.0 | 2160 | 102 |
| No. 4 | 0.9 | 610 | 140 | 2.0 | 2160 | 102 |
| No. 5 | 0.6 | 610 | 170 | 1.0 | 2160 | 102 |
Table 2 Preparation process parameters of GNPs/Mg composites
| Number | c (%) | T (℃) | R (r/min) | V (m/s) | F (kN) | G (MPa) |
|---|---|---|---|---|---|---|
| No. 1 | 0.0 | 610 | 140 | 2.0 | 2160 | 102 |
| No. 2 | 0.3 | 610 | 140 | 2.0 | 2160 | 102 |
| No. 3 | 0.6 | 610 | 140 | 2.0 | 2160 | 102 |
| No. 4 | 0.9 | 610 | 140 | 2.0 | 2160 | 102 |
| No. 5 | 0.6 | 610 | 170 | 1.0 | 2160 | 102 |
| Number | c (wt%) | icorr (A/cm2) | Ecorr (V) |
|---|---|---|---|
| No. 1 | 0.0 | 2.83 × 10-4 | - 1.42 |
| No. 2 | 0.3 | 8.25 × 10-4 | - 1.44 |
| No. 3 | 0.6 | 4.94 × 10-4 | - 1.43 |
| No. 4 | 0.9 | 9.48 × 10-4 | - 1.44 |
| No. 5 | 0.6 after | 1.28 × 10-4 | - 1.41 |
Table 3 Electrochemical parameters of potentiodynamic polarization fitted by cathode tafel extrapolation
| Number | c (wt%) | icorr (A/cm2) | Ecorr (V) |
|---|---|---|---|
| No. 1 | 0.0 | 2.83 × 10-4 | - 1.42 |
| No. 2 | 0.3 | 8.25 × 10-4 | - 1.44 |
| No. 3 | 0.6 | 4.94 × 10-4 | - 1.43 |
| No. 4 | 0.9 | 9.48 × 10-4 | - 1.44 |
| No. 5 | 0.6 after | 1.28 × 10-4 | - 1.41 |
Fig. 2 Metallographic structure diagrams of GNPs/Mg composites: a No. 1, b No. 2, c No. 3, d No. 4. e SEM image and X-ray mapping of No. 4 with 0.9 wt% GNPs: f Mg, g Al, h C
Fig. 3 a SEM image of No. 2 with 0.3 wt% GNPs. b The corresponding magnification back scattered image of the square in a. c SEM image of No. 3 with 0.6 wt% GNPs. d The corresponding magnification back scattered image of the square in c. e SEM image and X-ray mapping of No. 3 with 0.6 wt% GNPs: f Mg, g Al, h C
Fig. 4 a SEM image of No. 5 with 0.6 wt% GNPs after process adjustment. b and c Magnification images of the rectangular regions corresponding to a and b, respectively. The corresponding EDS analysis for point A is shown in the insets of b. The corresponding back scattered SEM image is shown in the insets of c. d X-ray mapping of Mg, Al, O, C for c
| Number | c (wt%) | Rs (Ω·cm2) | Rf (Ω·cm2) | Rct (Ω·cm2) |
|---|---|---|---|---|
| No. 1 | 0.0 | 0.34 | 21.7 | 489.6 |
| No. 2 | 0.3 | 0.35 | 19.89 | 243.5 |
| No. 3 | 0.6 | 0.42 | 19.67 | 367.4 |
| No. 4 | 0.9 | 0.42 | 16.12 | 288.5 |
| No. 5 | 0.6 after | 0.34 | 30.09 | 639.1 |
Table 4 Electrochemical parameters of electrochemical impedance spectra of GNPs/Mg composites fitted by equivalent circuits via Zview2
| Number | c (wt%) | Rs (Ω·cm2) | Rf (Ω·cm2) | Rct (Ω·cm2) |
|---|---|---|---|---|
| No. 1 | 0.0 | 0.34 | 21.7 | 489.6 |
| No. 2 | 0.3 | 0.35 | 19.89 | 243.5 |
| No. 3 | 0.6 | 0.42 | 19.67 | 367.4 |
| No. 4 | 0.9 | 0.42 | 16.12 | 288.5 |
| No. 5 | 0.6 after | 0.34 | 30.09 | 639.1 |
Fig. 9 a and i SEM images of the bright area. The corresponding X-ray mapping: b Mg, c Al, d Zn, e C, f P, g Ca, h O. j-l Corresponding EDS analysis for different points in i
Fig. 12 Phase-field simulated solute field evolution with different $\varphi_{0}$: a $\varphi_{0} = 2\pi$, c $\varphi_{0} = 2\pi \Delta t/500\Delta t$, $t_{{{\text{max}}}} = 50000\Delta t$. b and d Corresponding phase-field profiles at $t = 50000\Delta t$ with different $\varphi_{0}$
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