A Comparison Study of Hydrogen Storage Thermodynamics and Kinetics of YMg11Ni Alloy Prepared by Melt Spinning and Ball Milling

doi:10.1007/s40195-017-0638-8

Abstract

Abstract:

Melt spinning (MS) and ball milling (BM) were employed to fabricate YMg₁₁Ni alloy, and their structures and hydrogen storage performances were examined. The results reveal that the as-spun and as-milled alloys both exhibit the nanocrystalline and amorphous structure. The as-milled alloy shows a larger hydrogen absorption capacity as compared with the as-spun alloy. More than that, the as-milled alloy exhibits lower onset hydrogen desorption temperature than the as-spun one, which are 549.8 and 560.9 K, respectively. Additionally, the as-milled alloy shows a superior hydrogen desorption property to the as-spun one. On the basis of the time needed by desorbing hydrogen of 3 wt% H₂, for the as-milled alloy, it needs 1106, 456, 343, and 180 s corresponding to hydrogen desorption temperatures of 593, 613, 633, and 653 K. However, for the as-spun alloy, the time needed is greater than 2928, 842, 356, and 197 s corresponding to the same temperatures. Hydrogen desorption activation energies of as-milled and as-spun alloys are 98.01 and 105.49 kJ/mol, respectively, which is responsible for that the as-milled alloy possesses a much faster dehydriding rate. By means of the measurement of pressure-composition-temperature (P-C-T) curves, the dehydrogenation enthalpy change of the alloys prepared by MS (ΔH _de(MS)) and BM (ΔH _de(BM)) is 81.84 and 79.46 kJ/mol, respectively, viz. ΔH _de(MS) > ΔH _de(BM).

Key words: Mg-based alloy, Ball milling, Melt spinning, Hydrogen storage kinetics, Comparison

Yang-Huan Zhang, Wei Zhang, Jin-Liang Gao, Ze-Ming Yuan, Wen-Gang Bu, Yan Qi. A Comparison Study of Hydrogen Storage Thermodynamics and Kinetics of YMg₁₁Ni Alloy Prepared by Melt Spinning and Ball Milling[J]. Acta Metallurgica Sinica (English Letters), 2017, 30(11): 1040-1048.

Figures/Tables 9

Fig. 1 XRD profiles of a as-spun and b as-milled YMg11Ni alloys before and after hydrogen absorption and desorption

Fig. 2 HRTEM micrographs and SAD patterns of YMg11Ni alloy at different states: a as-spun YMg11Ni, b as-spun and hydrogenated YMg11Ni, c as-spun and dehydrogenated YMg11Ni, d as-milled YMg11Ni, e as-milled and hydrogenated YMg11Ni, f as-milled and dehydrogenated YMg11Ni

Fig. 3 Hydrogen absorption kinetic curves of a as-spun and b as-milled YMg11Ni alloys at different temperatures

Fig. 4 Temperature-programmed desorption curves of as-spun and as-milled YMg11Ni alloys after hydrogen absorption at a heating rate of 5 K/min

Fig. 5 Hydrogen desorption kinetic curves of a as-spun and b as-milled YMg11Ni alloys at different temperatures

Fig. 6 JMA graphs and Arrhenius plots of a as-spun and b as-milled YMg11Ni alloys (The insets show the Arrhenius plots)

Fig. 7 DSC curves and Kissinger plots of a as-spun and b as-milled YMg11Ni alloys at various heating rates (The insets show the Kissinger plots)

Fig. 8 P-C-T curves and van’t Hoff plots of a as-spun and b as-milled YMg11Ni alloys in the temperature range of 593-653 K

Table 1 Enthalpy change (ΔH) and entropy change (ΔS) of as-spun and as-milled alloys

State	ΔH_ab (kJ/mol)	ΔS_ab (J/mol/K)	ΔH_de (kJ/mol)	ΔS_de (J/mol/K)
As-spun	-78.63	-121.87	81.84	126.62
As-milled	-77.83	-118.71	79.46	120.15

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A Comparison Study of Hydrogen Storage Thermodynamics and Kinetics of YMg₁₁Ni Alloy Prepared by Melt Spinning and Ball Milling

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