Acta Metallurgica Sinica (English Letters) ›› 2025, Vol. 38 ›› Issue (7): 1219-1236.DOI: 10.1007/s40195-025-01848-8
Special Issue: 钢铁专辑 2025
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Mengjun Chen1, Tingping Hou1(
), Shi Cheng1, Feng Hu1, Tao Yu2, Xianming Pan3, Yuanyuan Li1, Kaiming Wu1(
)
Received:2024-10-23
Revised:2025-01-07
Accepted:2025-01-11
Online:2025-07-10
Published:2025-04-14
Contact:
Tingping Hou, houtingping@wust.edu.cn;Kaiming Wu, wukaiming@wust.edu.cn
Mengjun Chen, Tingping Hou, Shi Cheng, Feng Hu, Tao Yu, Xianming Pan, Yuanyuan Li, Kaiming Wu. A Comprehensive Exploration of the Relationship between Microstructure Optimization and Strength Enhancement in Low-Density 5Al-5Mn Steel[J]. Acta Metallurgica Sinica (English Letters), 2025, 38(7): 1219-1236.
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| C | Si | Mn | Cr | Ni | Mo | Nb | Al | Fe |
|---|---|---|---|---|---|---|---|---|
| 0.29 | 1.54 | 5.08 | 0.29 | 0.24 | 0.25 | 0.024 | 4.94 | Bal. |
Table 1 Chemical composition of alloy (wt%)
| C | Si | Mn | Cr | Ni | Mo | Nb | Al | Fe |
|---|---|---|---|---|---|---|---|---|
| 0.29 | 1.54 | 5.08 | 0.29 | 0.24 | 0.25 | 0.024 | 4.94 | Bal. |
Fig. 1 a Phase volume fractions diagram of 0.3C-5Al-5Mn-1.5Si steel at equilibrium temperatures. FCC and BCC are considered α-ferrite and γ-austenite. b Heat treatment schematic of the Q&T process. The annealing temperatures are set to be I 980 °C, II 1080 °C, III 1180 °C
Fig. 2 a EBSD band contrast diagram (left) and phase distribution diagram (right) of 1080 °C annealed sample. b-d SEM micrographs of samples annealed at different temperatures: b 980 °C, c 1080 °C, d 1180 °C. BCC phase includes martensite (M) and δ-ferrite (δ-F), while the FCC phase is defined as retained austenite (RA). Block-like RA distributes at the edges of island-like M&RA mixtures while martensite occupies the interior regions
Fig. 3 EPMA line scan results of samples annealed at a 980 °C, b 1080 °C, c 1180 °C. The carbon concentration of δ-F is lowest, and the carbon concentration of M is slightly lower than that of RA due to partition in tempering
Fig. 4 XRD patterns and calculated retained austenite fraction and carbon content of the three groups of specimens a, c before, b, d after tensile test. The (220) γ peak is significantly weakened after tensile test
| Group | VM (vol.%) | Vδ (vol.%) | Before VA (vol.%) | After VA (vol.%) |
|---|---|---|---|---|
| 980 °C | 26.4 | 56.1 | 17.5 | 14.2 |
| 1080 °C | 44.4 | 42.6 | 13.0 | 10.5 |
| 1180 °C | 24.2 | 63.3 | 12.5 | 11.0 |
Table 2 Volume fraction of each tissue before and after the tensile test calculated from EBSD result
| Group | VM (vol.%) | Vδ (vol.%) | Before VA (vol.%) | After VA (vol.%) |
|---|---|---|---|---|
| 980 °C | 26.4 | 56.1 | 17.5 | 14.2 |
| 1080 °C | 44.4 | 42.6 | 13.0 | 10.5 |
| 1180 °C | 24.2 | 63.3 | 12.5 | 11.0 |
Fig. 8 Average grain size calculated by equivalent diameter, geometrically necessary dislocations (GND) density, and LAGBs and HAGBs percentage distinguished by the software AZtecCrystal [44] before (blue) and after (red) tensile test of different groups
Fig. 9 True stress-strain curves for three sample groups at tensile rates of a 2 mm/min and b 20 mm/min, c, d the corresponding yield strength, tensile strength, and elongation curves, e summary of UTS for medium-Mn steels with different Al contents (Mn < 12 wt%, Al > 3 wt%) [10,25,26,46,47,48,49,50,51]
| Annealing temperature (°C) | Tensile rate (mm/min) | Rm (MPa) | Rp0.2 (MPa) | A (%) |
|---|---|---|---|---|
| 980 | 2 | 1008 ± 45 | 689 ± 10 | 9.1 ± 0.4 |
| 20 | 1125 ± 63 | 744 ± 11 | 11.4 ± 0.5 | |
| 1080 | 2 | 1079 ± 36 | 985 ± 25 | 6.7 ± 0.3 |
| 20 | 1190 ± 56 | 1080 ± 32 | 8.9 ± 0.1 | |
| 1180 | 2 | 1036 ± 28 | 961 ± 22 | 5.3 ± 0.3 |
| 20 | 1021 ± 30 | 1011 ± 29 | 5.7 ± 0.5 |
Table 3 Tensile properties of samples under different annealing temperatures and tensile rates
| Annealing temperature (°C) | Tensile rate (mm/min) | Rm (MPa) | Rp0.2 (MPa) | A (%) |
|---|---|---|---|---|
| 980 | 2 | 1008 ± 45 | 689 ± 10 | 9.1 ± 0.4 |
| 20 | 1125 ± 63 | 744 ± 11 | 11.4 ± 0.5 | |
| 1080 | 2 | 1079 ± 36 | 985 ± 25 | 6.7 ± 0.3 |
| 20 | 1190 ± 56 | 1080 ± 32 | 8.9 ± 0.1 | |
| 1180 | 2 | 1036 ± 28 | 961 ± 22 | 5.3 ± 0.3 |
| 20 | 1021 ± 30 | 1011 ± 29 | 5.7 ± 0.5 |
Fig. 10 Fracture morphologies of the experimental steel at a tensile rate of 20 mm/min: a1, a2 980 °C, b1, b2 1080 °C, and c1, c2 1180 °C. The cleavage plane is highlighted by yellow dashed lines
Fig. 11 a TEM diagram of 1080 °C group before tensile test. Selected area electron diffraction patterns of b δ-F, c film-like RA, d block RA, respectively
Fig. 12 TEM diagram of 1080 °C group after tensile test. a Jagged retained austenite (RA) distributed at the edge of martensite and retained austenite (M&RA) mixture. b The deformation-induced martensite distributed around jagged RA. c, d Dislocation pile-ups and dislocation tangles at grain boundaries (GB) or the interface of δ-ferrite (δ-F) and M&RA mixture
Fig. 13 C-J model and modified C-J model of different groups: a1, a2 980 °C, b1, b2 1080 °C, c1, c2 1180 °C. I: stage one, II: stage two, R2: coefficient of determination
| Group | 980 °C | 1080 °C | 1180 °C |
|---|---|---|---|
| HM model | |||
| I Slope (n) | 0.56 | 1.04 | 1.20 |
| IISlope (n) | 0.28 | 0.32 | 0.64 |
| C-J model | |||
| I Slope (n-1) | −1.75 | −0.74 | −0.98 |
| II Slope (n-1) | −0.89 | −2.83 | −3.04 |
| Modified C-J model | |||
| I Slope (1-n) | −2.96 | −0.70 | −0.82 |
| II Slope (1-n) | −3.13 | −8.50 | −4.47 |
| ε (strain points) | |||
| Stage Ito I | 0.05187 | 0.04432 | 0.03818 |
Table 4 Slope and turning strain points for each stage of three simulation models
| Group | 980 °C | 1080 °C | 1180 °C |
|---|---|---|---|
| HM model | |||
| I Slope (n) | 0.56 | 1.04 | 1.20 |
| IISlope (n) | 0.28 | 0.32 | 0.64 |
| C-J model | |||
| I Slope (n-1) | −1.75 | −0.74 | −0.98 |
| II Slope (n-1) | −0.89 | −2.83 | −3.04 |
| Modified C-J model | |||
| I Slope (1-n) | −2.96 | −0.70 | −0.82 |
| II Slope (1-n) | −3.13 | −8.50 | −4.47 |
| ε (strain points) | |||
| Stage Ito I | 0.05187 | 0.04432 | 0.03818 |
Fig. 14 a Correlation of tensile strength with prior-austenite fraction. b Correlation of total elongation with transformed austenite fraction. (calculated from the data of EBSD in Table 2). Comparation of 1080 °C group and 1180 °C group samples in c tensile strength and d plasticity. Note that the areas of each phase in the pie are consistent with their volume fractions in the steel, and the bigger areas of red regions correspond to higher contribution to strength or plasticity
| Group | σ0 (MPa) | σs (MPa) | σg (MPa) | σd (MPa) | σcal (MPa) | σexp (MPa) | σmodified (MPa) | (σgσn)1/2 (MPa) |
|---|---|---|---|---|---|---|---|---|
| 980 °C | 53[ | 374 | 276.5 | 214 | 917.5 | 1125 | 1234 | 593 |
| 1080 °C | 53[ | 374 | 263.9 | 224 | 913.9 | 1190 | 1187 | 536 |
| 1180 °C | 53[ | 374 | 254.6 | 216 | 897.6 | 1021 | 964 | 321 |
Table 5 Comparation of tensile strength calculated using the original and modified equations of different groups; σcal, σs, σg and σd are calculated by Eqs. (S7-S10) in Supplementary Material
| Group | σ0 (MPa) | σs (MPa) | σg (MPa) | σd (MPa) | σcal (MPa) | σexp (MPa) | σmodified (MPa) | (σgσn)1/2 (MPa) |
|---|---|---|---|---|---|---|---|---|
| 980 °C | 53[ | 374 | 276.5 | 214 | 917.5 | 1125 | 1234 | 593 |
| 1080 °C | 53[ | 374 | 263.9 | 224 | 913.9 | 1190 | 1187 | 536 |
| 1180 °C | 53[ | 374 | 254.6 | 216 | 897.6 | 1021 | 964 | 321 |
Fig. 16 Mechanism during tensile deformation: a1-a3 980 °C, b1-b3 1080 °C, and c1-c3 1180 °C. OM and FM represent original martensite and fresh martensite formed during the TRIP effect
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