Fe-EBT Chelate Complex: A Novel Mean for Growth of α-FeOOH and γ-Fe2O3 Nanostructures

doi:10.1007/s40195-014-0141-4

Abstract

Abstract:

Acicular goethite (α-FeOOH) and worm-like maghamite (γ-Fe₂O₃) nanostructures have been prepared adopting a novel route, using Na₂[Fe(HL)₂(H₂O)₂] chelate complex in alkaline medium. It is found that concentration of hydrated Fe(III) ions increased with increasing temperature, which later play a key role in generation of different phases of iron oxide. Phase and morphology of the products are investigated using XRD, FTIR, SEM, and TEM analysis. Using UV-Vis spectra, various electronic transitions of goethite and maghamite particles are examined. Maghamite nanostructures exhibit superparamagnetic property at room temperature. On the basis of experimental observations and analytical data, growth mechanism of the nanostructures is discussed.

Key words: Iron oxide, Nanostructures, Chemical synthesis, Growth mechanism, Magnetic properties

Pandey Gajanan. Fe-EBT Chelate Complex: A Novel Mean for Growth of α-FeOOH and γ-Fe₂O₃ Nanostructures[J]. Acta Metallurgica Sinica (English Letters), 2014, 27(6): 1127-1133.

Figures/Tables 8

Fig. 1 XRD patterns of as-prepared α-FeOOH a and γ-Fe2O3 b nanostructures

Fig. 2 FTIR spectra of a α-FeOOH and γ-Fe2O3 materials; b magnified view of FTIR spectra

Fig. 3 a, b SEM images of as-prepared α-FeOOH; c-e TEM images of as-prepared α-FeOOH nanostructures

Fig. 4 a SEM image of as-prepared γ-Fe2O3; b-d TEM images of as-prepared γ-Fe2O3 nanostructures

Fig. 5 UV-Vis absorption spectra of as-synthesised α-FeOOH and γ-Fe2O3 materials

Fig. 6 Room temperature magnetic hysteresis loops of γ-Fe2O3

Fig. 7 Enol-azo and keto-hydrazone forms of the ligand H2L-

Fig. 8 Structure of Na2[Fe(HL)2(H2O)2] chelate complex

References 35

[1]	Y. Gao, D. Ma, G. Hu, P. Zhai, X. Bao, B. Zhu, B. Zhang, D.S. Su,Angew. Chem. Int. Ed. 50, 10236(2011)
[2]	N. Zhao, W. Ma, Z. Cui, W. Song, C. Xu, M. Gao, ACS Nano 3, 1775 (2009)
[3]	J. Hu, G. Chen, I.M.C. Lo, Water Res. 39, 4528(2005)
[4]	T. Kim, A. Magasinski, K. Jacob, G. Yushin, R. Tannenbaum, Carbon 52, 56 (2013)
[5]	J. Chen, L.N. Xu, W.Y. Li, X.L. Gou,Adv. Mater. 17, 582(2005)
[6]	H. Basti, L.B. Tahar, L.S. Smiri, F. Herbst,M.-J. Vaulay, F. Chau, S. Ammara, S. Benderbous, J. Colloids Interface Sci. 341, 248(2010)
[7]	S. Laurent, D. Forge, M. Port, A. Roch, C. Robic, L.V. Elst, R.N. Muller,Chem. Rev. 108, 2064(2008)
[8]	J. Dobson,Nat. Nanotechnol. 3, 139(2008)
[9]	C.S.S.R. Kumar, F. Mohammad,Drug Deliv. Rev. 63, 789(2011)
[10]	L. An-Hui, E.L. Salabas, F. Schüth,Angew. Chem. Int. Ed. 46, 1222(2007)
[11]	Y.W. Jun, Y.M. Huh, J.S. Choi, J.H. Lee, H.T. Song, S. Kim, S. Yoon, K.S. Kim, J.S. Shin, J.S. Suh, J. Cheon, J. Am.Chem.Soc. 127, 5732(2005)
[12]	R. Sun, J. Dittrich, M. Le-Huu, M.M. Mueller, J. Bedke, J. Kartenbeck, W.D. Lehmann, R. Krueger, M. Bock, R. Huss, C. Seliger, H.J. Grone, B. Misselwitz, W. Semmler, F. Kiessling,Invest. Radiol. 40, 504(2005)
[13]	U. Schwertmann, R.M. Cornell, The Iron Oxides: Structure, Properties, Reactions,Occurrences and Uses (Wiley, Weinheim, 2003)
[14]	F.M. Michel, V. Barron, J. Torrent, M.P. Morales, C.J. Serna, J.F. Boily, Q. Liu, A. Ambrosini, A.C. Cismasu, G.E. Brown Jr, Proc. Natl. Acad.Sci.USA 107, 2787 (2010)
[15]	J.S. Hu, L.S. Zhong, W.G. Song, L.J. Wan,Adv. Mater. 20, 2977(2008)
[16]	B. Wang, H. Wu, L. Yu, R. Xu, T.T. Lim, X. Wen (David) Lou, Adv. Mater. 24, 1111(2012)
[17]	M.F. Casula,Y.-W. Jun, D.J. Zaziski, E.M. Chan, A.A. Corrias, P. Alivisatos, J. Am. Chem. Soc. 128, 1675(2006)
[18]	Y. Oaki, H. Imai,Chem. Eur. J. 13, 8564(2007)
[19]	X. Mou, Y. Li, B. Zhang, L. Yao, X. Wei, D.S. Su, W. Shen, Eur. J. Inorg. Chem 2012, 2684(2012)
[20]	P.V. Adhyapak, U.P. Mulik, D.P. Amalnerkar, I.S. Mulla, J. Am.Ceram.Soc. 96, 731(2013)
[21]	J. Wang, L. Li, C.L. Wong, L. Sun, Z. Shen, S. Madhavi,RSC Adv. 3, 15316(2013)
[22]	M. Debabrata, M. Unnikrishnan, V. Srihari, S.D.Parukuttyamma Sujatha Devi, Cryst. Growth Des. 13, 3637(2013)
[23]	Y. Xiong, Y. Xie, S. Chen, Z. Li,Chem. Eur. J. 9, 4991(2003)
[24]	H. Diehl, K.F. Lidstrom,Anal. Chem. 31, 414(1959)
[25]	G. Pandey, S.K. Srivastava,Synth. React. Inorg., Met.-Org., Nano-Met. Chem. 36, 663(2006)
[26]	R.J. Bandaranayke, G.W. Wen, J.Y. Lin, H.X. Jiang, C.M. Sorensen,Appl. Phys. Lett. 67, 831(1995)
[27]	T.J. Daou, J.M. Greneche, G. Pourroy, S. Buathong, A. Derory, C. Ulhaq-Bouillet, B. Donnio, D. Guillon, S. Begin-Colin,Chem. Mater. 20, 5869(2008)
[28]	A.A. Khaleel,Chem. Eur. J. 10, 925(2004)
[29]	D. Fu, P.G. Keech, X. Sunb, J.C. Phys.Chem. Chem. Phys. 13, 18523(2011)
[30]	L. Verdonck, S. Hoste, F.F. Roelandt, G.P. Vander,Kelen. J. Mol. Struct. 79, 273(1982)
[31]	G. Pandey, K.K. Narang, J. Coord. Chem. 59, 1495(2006)
[32]	D.M. Shermon,Am. Mineral. 70, 1262(1985)
[33]	F. Geng, Z. Zhao, J. Geng, H. Cong,H.-M. Cheng, Mater. Lett. 61, 4794(2007)
[34]	J.G. Hockridge, F. Jones, M. Loan, W.R. Richmond, J. Cryst. Growth 311, 3876 (2009)
[35]	P.C. Rieke, B.D. Marsh, L.L. Wood, B.J. Tarasevich, J. Liu, L. Song, G.E. Fryxell, Langmuir 11, 318 (1995)

Fe-EBT Chelate Complex: A Novel Mean for Growth of α-FeOOH and γ-Fe₂O₃ Nanostructures

RichHTML

PDF (PC)

Knowledge

Abstract

Cite this article

share this article

Figures/Tables 8

References 35

Related Articles 15

Recommended Articles

Metrics

Comments

[1]	Shang Zhao, Zhaolin Wang, Mingliang Wang, Zeyu Ding, Yiping Lu. A critical review of advances and application prospects of soft magnetic high entropy alloys [J]. Metals Advances, 2026, 40(2): 1-7.
[2]	Zhaoyang Cheng, Jing Liu, Chunlei Yu, Bolin Zhong, Shenglin Chen, Bing Fu, Soran Birosca. Balancing Magnetic and Mechanical Properties of Non-oriented Electrical Steel: Correlation Between Microstructure and Properties [J]. Acta Metallurgica Sinica (English Letters), 2024, 37(12): 2136-2149.
[3]	Shuohong Gao, Xingchen Yan, Cheng Chang, Xinliang Xie, Qingkun Chu, Zhaoyang Deng, Bingwen Lu, Min Liu, Hanlin Liao, Nouredine Fenineche. Finished surface morphology, microstructure and magnetic properties of selective laser melted Fe-50wt% Ni permalloy [J]. Acta Metallurgica Sinica (English Letters), 2022, 35(9): 1439-1452.
[4]	Chenchen Xiong, Jing Bai, Yansong Li, Jianglong Gu, Xinzeng Liang, Ziqi Guan, Yudong Zhang, Claude Esling, Xiang Zhao, Liang Zuo. First-Principles Investigation on Phase Stability, Elastic and Magnetic Properties of Boron Doping in Ni-Mn-Ti Alloy [J]. Acta Metallurgica Sinica (English Letters), 2022, 35(7): 1175-1183.
[5]	Li-Cheng Wu, Yan-Hui Li, Xing-Jie Jia, Ai-Na He, Wei Zhang. Effects of Ribbon Thickness on Structure and Soft Magnetic Properties of a High-Cu-Content FeBCuNb Nanocrystalline Alloy [J]. Acta Metallurgica Sinica (English Letters), 2022, 35(2): 235-242.
[6]	Fuzhao Yan, Jing Li, Yiyi Li, Liangyin Xiong, Shi Liu. Formation Mechanism of Nanoparticles in Fe-Cr-Al ODS Alloy Fabricated by Direct Oxidation Method [J]. Acta Metallurgica Sinica (English Letters), 2021, 34(7): 963-972.
[7]	Li-Li Zhang, Jie Song, Sajjad Ur Rehman, Jia-Jie Li, Lei Wang, Mu-Nan Yang, Ren-Hui Liu, Qing-Zheng Jiang, Zhen-Chen Zhong. Uneven Evolution of Microstructure, Magnetic Properties and Coercivity Mechanism of Mo-Substituted Nd-Ce-Fe-B Alloys [J]. Acta Metallurgica Sinica (English Letters), 2021, 34(4): 590-596.
[8]	Man Zhu, Chi Zhang, Kun Li, Yongqin Liu, Mao Zhang, Lijuan Yao, Zengyun Jian. A Novel CoFe₂NiMn_0.3AlCu_x High-Entropy Alloy with Excellent Magnetic Properties and Good Mechanical Properties [J]. Acta Metallurgica Sinica (English Letters), 2021, 34(11): 1557-1564.
[9]	Liang Yang, Jun Li, Defang Tu, Joel C. J. Strickland, Qiaodan Hu, Hongbiao Dong, Jianguo Li. Reduced Annealing Time and Enhanced Magnetocaloric Effect of La(Fe, Al)₁₃ Alloy by La-nonstoichiometry and Si-doping [J]. Acta Metallurgica Sinica (English Letters), 2020, 33(11): 1535-1542.
[10]	Rui-Yang Liang, Ping Yang, Wei-Min Mao. Effect of Initial Goss Texture Sharpness on Texture Evolution and Magnetic Properties of Ultra-thin Grain-oriented Electrical Steel [J]. Acta Metallurgica Sinica (English Letters), 2017, 30(9): 895-906.
[11]	M. J. Miah, A. K. M. Akther Hossain. Magnetic, Dielectric and Complex Impedance Properties of xBa_0.95Sr_0.05TiO₃-(1 - x)BiFe_0.9Gd_0.1O₃Multiferroic Ceramics [J]. Acta Metallurgica Sinica (English Letters), 2016, 29(6): 505-517.
[12]	Hong-Fei Qi, Da-Bo Liu, Song-Yan Dai, Tian-Min Wang. Magnetic Properties of Co 2D Antidot Arrays with Hexagonal Holes Using Colloidal Crystal Template Method [J]. Acta Metallurgica Sinica (English Letters), 2016, 29(5): 409-421.
[13]	Qiu-Hong Wang, Chao-Long Tang, Cheng-Ming Jiang, Dan-Feng Du, Feng Wang, Jin-Hui Song. Role of Substrate Roughness in ZnO Nanowire Arrays Growth by Hydrothermal Approach [J]. Acta Metallurgica Sinica (English Letters), 2016, 29(3): 237-242.
[14]	Hossein Mostaan, Morteza Shamanian, Seyed Mahmoud Monirvaghefi, Peiman Behjati, Jerzy A. Szpunar, Morteza Amiri, Mashallah Fathi Moghadam. Structure, Texture and Magnetic Properties of Laser-Welded Ultrathin Fe-Co-V Foils [J]. Acta Metallurgica Sinica (English Letters), 2015, 28(3): 338-347.
[15]	Nikolay Velinov, Dimitar Dimitrov, Kremena Koleva, Krassimir Ivanov, Ivan Mitov. Mechanochemical Synthesis and Characterization of Nanocrystalline Copper-Cobalt Ferrites [J]. Acta Metallurgica Sinica (English Letters), 2015, 28(3): 367-372.