Acta Metallurgica Sinica (English Letters) ›› 2022, Vol. 35 ›› Issue (10): 1617-1630.DOI: 10.1007/s40195-022-01394-7
Special Issue: 2022年高熵合金专辑; 复合材料 2022
Previous Articles Next Articles
Shaofan Ge1,2, Shifeng Lin1, Huameng Fu1,3,4(
), Long Zhang1, Tieqiang Geng1, Zhengwang Zhu1,3,4, Zhengkun Li1,3, Hong Li1,3(
), Aimin Wang1,3,4, Hongwei Zhang1,3,4, Haifeng Zhang1,3,4
Received:2021-11-05
Revised:2021-12-10
Accepted:2021-12-27
Online:2022-04-09
Published:2022-04-09
Contact:
Huameng Fu,Hong Li
About author:Hong Li, lihong@imr.ac.cnShaofan Ge, Shifeng Lin, Huameng Fu, Long Zhang, Tieqiang Geng, Zhengwang Zhu, Zhengkun Li, Hong Li, Aimin Wang, Hongwei Zhang, Haifeng Zhang. High-temperature Mechanical Properties and Dynamic Recrystallization Mechanism of in situ Silicide-reinforced MoNbTaTiVSi Refractory High-entropy Alloy Composite[J]. Acta Metallurgica Sinica (English Letters), 2022, 35(10): 1617-1630.
Add to citation manager EndNote|Ris|BibTeX
Fig. 2 Microstructure of MoNbTaTiVSi refractory high-entropy alloy composite after 1200 °C annealing: a BSE image at lower magnification, b BSE image of eutectic area at higher magnification, c HADDF image of eutectic area, d EDS mapping of b, e and g HR image of the BCC phase and the Ti5Si3 phase, f and h SAED patterns of the BCC phase and the Ti5Si3 phase
| Element | Melting temperature, Tm (°C)[62] | Average (at.%) | Dendritic (white) phase (at.%) | Dark phase (at.%) | $\Delta {H}_{\mathrm{mix}}$ with Si (kJ/mol) [31] |
|---|---|---|---|---|---|
| Si | 1414 | 18 | 3.82 | 30.45 | |
| Ti | 1668 | 18.01 | 10.27 | 28.15 | - 66 |
| V | 1910 | 17.6 | 22.4 | 12.96 | - 48 |
| Nb | 2477 | 14.27 | 13.82 | 14.22 | - 56 |
| Mo | 2623 | 14.05 | 22.96 | 5.58 | - 36 |
| Ta | 3017 | 18.07 | 26.72 | 8.64 | - 56 |
Table 1 Chemical composition of each phase and the mixing enthalpy between Si and other elements
| Element | Melting temperature, Tm (°C)[62] | Average (at.%) | Dendritic (white) phase (at.%) | Dark phase (at.%) | $\Delta {H}_{\mathrm{mix}}$ with Si (kJ/mol) [31] |
|---|---|---|---|---|---|
| Si | 1414 | 18 | 3.82 | 30.45 | |
| Ti | 1668 | 18.01 | 10.27 | 28.15 | - 66 |
| V | 1910 | 17.6 | 22.4 | 12.96 | - 48 |
| Nb | 2477 | 14.27 | 13.82 | 14.22 | - 56 |
| Mo | 2623 | 14.05 | 22.96 | 5.58 | - 36 |
| Ta | 3017 | 18.07 | 26.72 | 8.64 | - 56 |
Fig. 3 a Engineering stress-strain curves tested at room temperature, 800 °C, 1000 °C and 1200 °C, b temperature dependence of specific yield stress for refractory HEAs [2,19,36,37,38,39,40,41,42,43,44]
Fig. 4 Microstructures of the composite after 1200 °C compression test with the strain at 0.5: a BSE image, b HADDF image of eutectic area, c BF image of the same area of b, d BF image for the example of LAGBs surrounded dislocation cell in the Ti5Si3 phase, e BF image for the example of bulging grain boundaries in the Ti5Si3 phase. The yellow circles mark the nuclei of dynamic recrystallized BCC phase
Fig. 6 EBSD results of HD10 and HD50 compression specimen: a, e IPF maps, b, f phase maps, c,g pole figures of the BCC phase, d, h pole figures of the Ti5Si3 phase
Fig. 7 a-g Recrystallized fraction maps for HD 10 and HD50, a, e whole detected area, b, f BCC phases, c, g Ti5Si3 phases, d, h strain contouring maps for HD 10 and HD50
Fig. 8 Detail of selected eutectic area as indicated by black frames in Fig. 7(d, h), a, b recrystallized fraction maps, e, g phase maps, f, h local misorientation maps, i, j band contrast map blended with grain boundary map
| [1] | J.W. Yeh, S.K. Chen, S.J. Lin, J.Y. Gan, T.S. Chin, T.T. Shun, C.H. Tsau, S.Y. Chang, Adv. Eng. Mater. 6, 299 (2004) |
| [2] | O.N. Senkov, G.B. Wilks, J.M. Scott, D.B. Miracle,Intermetallics 19, 698 (2011) |
| [3] | P. Shi, R. Li, Y. Li, Y. Wen, Y. Zhong, W. Ren, Z. Shen, T. Zheng, J. Peng, X. Liang, P. Hu, N. Min, Y. Zhang, Y. Ren, P.K. Liaw, D. Raabe, Y.D. Wang,Science 373, 912 (2021) |
| [4] | Y.L. Zhao, T. Yang, Y.R. Li, L. Fan, B. Han, Z.B. Jiao, D. Chen, C.T. Liu, J.J. Kai, Acta Mater. 188, 517 (2020) |
| [5] | H. Wan, D. Song, X. Shi, Y. Cai, T. Li, C. Chen, J. Mater. Sci. Technol. 60, 197 (2021) |
| [6] | C. Xiang, Z.M. Zhang, H.M. Fu, E.H. Han, J.Q. Wang, H.F. Zhang, G.D. Hu, Acta Metall. Sin. -Engl. Lett. 32, 1053 (2019) |
| [7] | A. Raphel, S. Kumaran, K.V. Kumar, L. Varghese, Mater. Today: Proc. 4, 195 (2017) |
| [8] | S.K. Varma, F. Sanchez, S. Moncayo, C.V. Ramana, J. Mater. Sci. Technol. 38, 189 (2020) |
| [9] | J. Pang, T. Xiong, X. Wei, Z. Zhu, B. Zhang, Y. Zhou, X. Shao, Q. Jin, S. Zheng, X. Ma, Materialia 6 (2019). |
| [10] | Z.J. Zhang, E.H. Han, C. Xiang, J. Mater. Sci. Technol. 84, 230 (2021) |
| [11] | Y. Ji, L. Zhang, X. Lu, H. Fu, Z. Zhu, H. Li, H. Zhang, H. Zhang,Intermetallics 138, 107339 (2021) |
| [12] | S. Li, J. Li, J. Shi, Y. Peng, X. Peng, X. Sun, F. Jin, J. Xiong, F. Zhang, J. Mater. Sci. Technol. 96, 140 (2022) |
| [13] | H. Jiang, D.X. Qiao, W.N. Jiao, K.M. Han, Y.P. Lu, P.K. Liaw, J. Mater. Sci. Technol. 61, 119 (2021) |
| [14] | J.Y. Pang, H.W. Zhang, L. Zhang, Z.W. Zhu, H.M. Fu, H. Li, A.M. Wang, Z.K. Li, H.F. Zhang, J. Mater. Sci. Technol. 78, 74 (2021) |
| [15] | J.M. Zhu, H.M. Fu, H.F. Zhang, A.M. Wang, H. Li, Z.Q. Hu, J. Alloys Compd. 509, 3476 (2011) |
| [16] | Y. Zhang, Y. Liu, Y.X. Li, X. Chen, H.W. Zhang, Mater. Lett. 174, 82 (2016) |
| [17] | N.N. Guo, L. Wang, L.S. Luo, X.Z. Li, R.R. Chen, Y.Q. Su, J.J. Guo, H.Z. Fu, J. Alloys Compd. 660, 197 (2016) |
| [18] | X.D. Sun, H.G. Zhu, J.L. Li, J.W. Huang, Z.H. Xie, Mater. Chem. Phys. 220, 449 (2018) |
| [19] | Y. Liu, Y. Zhang, H. Zhang, N. Wang, X. Chen, H. Zhang, Y. Li, J. Alloys Compd. 694, 869 (2017) |
| [20] | C.M. Liu, H.M. Wang, S.Q. Zhang, H.B. Tang, A.L. Zhang, J. Alloys Compd. 583, 162 (2014) |
| [21] | J.M. Zhu, H.M. Fu, H.F. Zhang, A.M. Wang, H. Li, Z.Q. Hu, Mater. Sci. Eng. A 527, 7210 (2010) |
| [22] | L. Zhang, J. Wu, Acta Mater. 46, 3535 (1998) |
| [23] | K. Guan, L. Jia, B. Kong, S. Yuan, H. Zhang, Mater. Sci. Eng. A 663, 98 (2016) |
| [24] | Y. Jiao, L.J. Huang, S.L. Wei, L. Geng, M.F. Qian, S. Yue, Corros. Sci. 140, 223 (2018) |
| [25] | Y. Jiao, L.J. Huang, Q. An, S. Jiang, Y.N. Gao, X.P. Cui, L. Geng, Mater. Sci. Eng. A 673, 595 (2016) |
| [26] | S.I. Wright, M.M. Nowell, D.P. Field, Microsc. Microanal. 17, 316 (2011) |
| [27] | D. Field, L. Bradford, M. Nowell, T. Lillo, Acta Mater. 55, 4233 (2007) |
| [28] | N.N. Guo, L. Wang, L.S. Luo, X.Z. Li, R.R. Chen, Y.Q. Su, J.J. Guo, H.Z. Fu, Mater. Sci. Eng. A 651, 698 (2016) |
| [29] | K. Kishida, M. Fujiwara, H. Adachi, K. Tanaka, H. Inui, Acta Mater. 58, 846 (2010) |
| [30] | W. Zhang, P.K. Liaw, Y. Zhang, Sci. China Mater. 61, 2 (2018) |
| [31] | A. Takeuchi, A. Inoue, Mater. Trans. 46, 2817 (2005) |
| [32] | R. Rosenkranz, G. Frommeyer, W. Smarsly,High Temp. Aluminides Intermet., Proc. Symp. 152, 288 (1992). |
| [33] | P. Rodriguez, Bull. Mater. Sci.6, 653 (1984) |
| [34] | S. Wei, J. Kim, C.C. Tasan, Acta Mater. 168, 76 (2019) |
| [35] | H. J. McQueen, J. J. Jonas, ed. by R. J. Arsenault, plastic deformation of materials, (ACADEMIC PRESS, London, 1975), p. 393. |
| [36] | O.N. Senkov, J.M. Scott, S.V. Senkova, F. Meisenkothen, D.B. Miracle, C.F. Woodward, J. Mater. Sci.47, 4062 (2012) |
| [37] | C.C. Juan, M.H. Tsai, C.W. Tsai, C.M. Lin, W.R. Wang, C.C. Yang, S.K. Chen, S.J. Lin, J.W. Yeh,Intermetallics 62, 76 (2015) |
| [38] | Z.D. Han, N. Chen, S.F. Zhao, L.W. Fan, G.N. Yang, Y. Shao, K.F. Yao,Intermetallics 84, 153 (2017) |
| [39] | O.A. Waseem, J. Lee, H.M. Lee, H.J. Ryu, Mater. Chem. Phys. 210, 87 (2018) |
| [40] | M. Wang, Z. Ma, Z. Xu, X. Cheng, J. Alloys Compd. 803, 778 (2019) |
| [41] | S. Das, P.S. Robi, Int. J. Refract. Met. Hard Mater. 100, 105656 (2021) |
| [42] | B. Kang, T. Kong, H.J. Ryu, S.H. Hong, J. Mater. Sci. Technol. 69, 32 (2021) |
| [43] | O.N. Senkov, J. Gild, T.M. Butler, J. Alloys Compd. 862, 158003 (2021) |
| [44] | S. Wu, D. Qiao, H. Zhao, J. Wang, Y. Lu, J. Alloys Compd. 889, 161800 (2021) |
| [45] | Z. Guo, A. Zhang, J. Han, J. Meng, J. Mater. Sci.54, 10077 (2019) |
| [46] | D.W. Suh, T. Inoue, S. Torizuka, A. Ohmori, K. Nagai, ISIJ Int. 42, 1026 (2002) |
| [47] | P. Cizek, B.P. Wynne, Mater. Sci. Eng. A 230, 88 (1997) |
| [48] | F. J. Humphreys, M. Hatherly, ed. by F. J. Humphreys and M. Hatherly(Eds.), Recrystallization and related annealing phenomena, (Elsevier, Oxford, 2004), p. 415. |
| [49] | J.L. Qu, X.F. Xie, Z.N. Bi, J.H. Du, M.C. Zhang, J. Alloys Compd. 785, 918 (2019) |
| [50] | A.M. Wusatowska-Sarnek, H. Miura, T. Sakai, Mater. Sci. Eng. A 323, 177 (2002) |
| [51] | J. Chen, J. Dong, M. Zhang, Z. Yao, Mater. Sci. Eng. A 673, 122 (2016) |
| [52] | F. Gao, Y.R. Xu, B.Y. Song, K.N. Xia, Metall. Mater. Trans. A 31, 21 (2000) |
| [53] | X.Y. Yang, H. Miura, T. Sakai, Mater. Trans. 43, 2400 (2002) |
| [54] | K. Huang, R.E. Logé, Mater. Des. 111, 548 (2016) |
| [55] | W. Blum, Q. Zhu, R. Merkel, H.J. McQueen, Mater. Sci. Eng. A 205, 23 (1996) |
| [56] | A. Gholinia, F. Humphreys, P.B. Prangnell, Acta Mater. 50, 4461 (2002) |
| [57] | M.E. Kassner, S.R. Barrabes, Mater. Sci. Eng. A 410, 152 (2005) |
| [58] | E. Antillon, C. Woodward, S. I. Rao, B. Akdim, Acta Mater. 215 (2021). |
| [59] | W. Huang, J. Chen, H. Yan, W. Xia, B. Su, W. Zhu, Met. Mater. Int. 26, 747 (2019) |
| [60] | Y.X. Huang, Y.B. Wang, X.C. Meng, L. Wan, J. Cao, L. Zhou, J.C. Feng, J. Mater. Process. Technol. 249, 331 (2017) |
| [61] | A.A. Khamei, K. Dehghani, J. Alloys Compd. 490, 377 (2010) |
| [62] | The periodic table of the elements, https://www.webelements.com. |
| [1] | X.L. Wang, J.Y. Li, Q.S. Mei. Recent progress in Zn matrix composites for biomedical applications [J]. Metals Advances, 2026, 39(1): 26-37. |
| [2] | Yuanyuan Feng, Jianchao Pang, Xiaoyuan Teng, Chenglu Zou, Jingjing Liang, Yuping Zhu, Shouxin Li, Jinguo Li, Zhefeng Zhang. Quasi-in-situ EBSD Study on the Microstructure and Tensile Properties of Selective Laser Melted Inconel 718 Alloy Processed by Different Heat Treatments [J]. Acta Metallurgica Sinica (English Letters), 2025, 38(9): 1499-1512. |
| [3] | F. S. Li, L. H. Wu, Y. Kan, H. B. Zhao, D. R. Ni, P. Xue, B. L. Xiao, Z. Y. Ma. Microstructure Evolution and Fracture Mechanisms in Electron Beam Welded Joint of Ti-6Al-4V ELI Alloy Ultra-thick Plates [J]. Acta Metallurgica Sinica (English Letters), 2025, 38(8): 1317-1330. |
| [4] | Haoyu Cheng, Chenyang Hou, Jianlei Zhang, Xiaodong Mao, Yuanxiang Zhang, Yanyun Zhao, Chulun Shen, Changjiang Song. An Innovative Large-Scale Preparation Method for ODS Steel: Zone Melting with Built-In Precursor Powder [J]. Acta Metallurgica Sinica (English Letters), 2025, 38(8): 1397-1409. |
| [5] | Haoran Pang, Liwei Lu, Gongji Yang, Xiaojun Wang, Wen Wang, Hua Zhang, Yujuan Wu. Amelioration of Mechanical Properties of Rolled Mg-4.5Al-2.5Zn Alloy by Cryogenic Cycling Treatment [J]. Acta Metallurgica Sinica (English Letters), 2025, 38(8): 1436-1452. |
| [6] | Qi Zhou, Yufeng Xia, Yu Duan, Baihao Zhang, Yuqiu Ye, Peitao Guo, Lu Li. Microstructure and Mechanical Properties of Yb-Containing AZ80 Cast Alloys [J]. Acta Metallurgica Sinica (English Letters), 2025, 38(7): 1095-1108. |
| [7] | Mengjun Chen, Tingping Hou, Shi Cheng, Feng Hu, Tao Yu, Xianming Pan, Yuanyuan Li, Kaiming Wu. A Comprehensive Exploration of the Relationship between Microstructure Optimization and Strength Enhancement in Low-Density 5Al-5Mn Steel [J]. Acta Metallurgica Sinica (English Letters), 2025, 38(7): 1219-1236. |
| [8] | Wei Pan, Bin Xu, Chong Li. Effects of Groove Shape on Microstructure and Mechanical Responses of Laser-Directed Energy Deposition-Repaired GH4099 Ni-Based Superalloy [J]. Acta Metallurgica Sinica (English Letters), 2025, 38(6): 1003-1011. |
| [9] | Hongyang Zhang, Huihui Nie, Zhijian Li, Hongsheng Chen, Wei Liang, Liuwei Zheng. Evolution of Microstructure and Mechanical Properties of AZ31 Sheets with Different Initial Microstructures During the Corrugated Wide Limit Alignment Process [J]. Acta Metallurgica Sinica (English Letters), 2025, 38(6): 1012-1028. |
| [10] | Xiang Fei, Naicheng Sheng, Zhaokuang Chu, Han Wang, Shijie Sun, Yuping Zhu, Shigang Fan, Jinjiang Yu, Guichen Hou, Jinguo Li, Yizhou Zhou, Xiaofeng Sun. Design Strategy for Synergistic Strengthening of W and Al in High-W Superalloys [J]. Acta Metallurgica Sinica (English Letters), 2025, 38(6): 1057-1068. |
| [11] | Yao Zhang, Hongtao Wang, Zhongtao Lu, Zifeng Li, Pengfei Wen, Xiaobin Feng, Guodong Li, Bo Duan, Pengcheng Zhai. Effect of Ag Vacancies on the Mechanical Properties of Ag2S Thermoelectric Semiconductor [J]. Acta Metallurgica Sinica (English Letters), 2025, 38(5): 869-875. |
| [12] | Yaoxiang Geng, Keying Lv, Chunfeng Zai, Zhijie Zhang, Anil Kunwar. A High-Strength TiB2-Modified Al-Si-Mg-Zr Alloy Fabricated by Laser Powder-Bed Fusion [J]. Acta Metallurgica Sinica (English Letters), 2025, 38(4): 542-554. |
| [13] | Haijian Liu, Tianle Li, Xifeng Li, Huiping Wu, Zhiqiang Wang, Jun Chen. Strength Optimization of Diffusion-Bonded Ti2AlNb Alloy by Post-Heat Treatment [J]. Acta Metallurgica Sinica (English Letters), 2025, 38(4): 614-626. |
| [14] | X. W. Shang, Z. G. Lu, R. P. Guo, L. Xu. Influence of Hot Isostatic Pressing Temperature on Microstructure and Mechanical Properties of Ti-6.5Al-3.5Mo-1.5Zr-0.3Si Alloy [J]. Acta Metallurgica Sinica (English Letters), 2025, 38(4): 627-641. |
| [15] | Jing Wang, Xuejian Wang, Zongning Chen, Huijun Kang, Tongmin Wang, Enyu Guo. In Vitro Corrosion Behavior and Mechanical Property of Novel Mg-Sn-In-Ga Alloys for Orthopedic Applications [J]. Acta Metallurgica Sinica (English Letters), 2025, 38(3): 353-366. |
| Viewed | ||||||
|
Full text |
|
|||||
|
Abstract |
|
|||||
WeChat
