Ternary Metal-Organic Framework Derived 2D Fe2O3/Co3O4/NiO/NC Heterostructured Nanosheets for Super Lithium Storage

doi:10.1007/s40195-021-01365-4

Abstract

Abstract:

Fe₂O₃/Co₃O₄/NiO/NC nanosheets have been successfully prepared via a two-step annealing process of ternary metal coordination polymer. Attributing to the synergistic effects of the multiple metal oxides and the unique 2D nanosheet structure, the improved electrical conductivity and effective electron/ion transfer enables Fe₂O₃/Co₃O₄/NiO/NC electrode to exhibit excellent electrochemical properties with outstanding rate capacity and cycling stability. This work may pave the way to construct ternary metal oxide electrode material with an excellent electrochemical performance by introducing multiple metal oxides.

Key words: Nanosheets, Ternary metal-organic framework, Lithium-ion batteries, Fe₂O₃, Co₃O₄, NiO, NC, Ternary metal oxide

Yongjun Zheng, Rui Sun, Zhaoxia Qin, Xinlong Liu, Yufei Zhang, Haibin Wang, Haosen Fan. Ternary Metal-Organic Framework Derived 2D Fe₂O₃/Co₃O₄/NiO/NC Heterostructured Nanosheets for Super Lithium Storage[J]. Acta Metallurgica Sinica (English Letters), 2022, 35(8): 1376-1382.

Figures/Tables 4

Fig. 1 a-c SEM images, d-f TEM images, g-l TEM elemental mapping of Fe2O3/Co3O4/NiO/NC nanosheets

Fig. 2 a XPS survey spectrum, b Fe 2p, c Co 2p, d Ni 2p, e, C1s, f N 1s of the Fe2O3/Co3O4/NiO/NC nanosheets

Fig. 3 a, b CV curves of Fe2O3/Co3O4/NiO/NC and Co3O4/NiO/NC at the scan rate of 0.1 mV s-1, c charge/discharge curves of Fe2O3/Co3O4/NiO/NC nanosheets at the current density of 0.1 A g-1, d rate performance from 0.1 to 5 A g-1, e comparison of rate capability for the Fe2O3/Co3O4/NiO/ nanosheets electrode with various anodes in previous literature, f long-term cyclic stability at the 1 A g-1 of the materials, g long-term cyclic stability at the 2 A g-1 of the materials

Fig. 4 a CV curves at different scan rates, b corresponding logarithm (peak current) versus logarithm (scan rate) plots at different peaks of the Fe2O3/Co3O4/NiO/NC nanosheets, c pseudocapacitive contribution at different scan rates, and d pseudocapacitive contribution at 0.8 mV/s

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Ternary Metal-Organic Framework Derived 2D Fe₂O₃/Co₃O₄/NiO/NC Heterostructured Nanosheets for Super Lithium Storage

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