Acta Metallurgica Sinica (English Letters) >
Corrosion Inhibition of Leucaena Leucocephala Pod on Mild Steel in Sulphuric Acid Solution
Received date: 2013-02-07
Revised date: 2013-04-08
Online published: 2013-07-11
The corrosion of the mild steel in 1 mol/L H2SO4 was investigated using Leucaena leucocephala pod extract (LLPE) as corrosion inhibitor by weight loss and electrochemical techniques. Inhibition efficiency of 95 % was achieved with 500×10- 6 of LLPE at 308 K. The polarization studies showed that LLPE acted as mixed type inhibitor. The adsorption of the studied inhibitor on mild steel obeyed Langmuir adsorption isotherm. Protective film formation against acid attack was confirmed by FT-IR, XRD and SEM techniques.
Key words： Mild steel; Polarization; SEM; Acid corrosion; XRD
P. Muthukrishnan , B. Jeyaprabha , P. Prakash . Corrosion Inhibition of Leucaena Leucocephala Pod on Mild Steel in Sulphuric Acid Solution[J]. Acta Metallurgica Sinica (English Letters), 2013 , 26(4) : 416 -424 . DOI: 10.1007/s40195-013-0082-3
[1]F. Kandemirli and S. Sagdinc, Corros. Sci.49(2007) 2118.
[2]M. Bouklash, B. Hammoutim, M. Benkaddour and T.Benhadda, J Appl. Electrochem.35(2005) 1095.
[3]H.A. Sorkhabi, D. Seifzadeh and M.G. Hosseini, Corros.Sci.50(2008) 3363.
[4]M.A. Quraishi and D. Jamal, J. Appl. Electrochem. 32(2002) 425.
[5]M. Elayyachy, A. El Idrissi and B. Hammouti, Corros. Sci.48(2006) 2470.
[6]K.C. Emregul and M. Hayvali, Corros. Sci.48(2006) 797.
[7]M.E. Azhar, M. Mernari, M. Traisnel, F. Bentiss and M.Lagrenee, Corros. Sci.43(2001) 2229.
[8]P.R. Roberge, Corrosion Inhibitors, Handbook of CorrosionEngineering, McGraw Hill, New York, 1999, pp. 833-862.
[9]H.A. Sorkhabi and E. Asghari, Electrochim. Acta.54(2008) 162.
[10] E.E. Oguzie, Mater. Chem. Phys.99(2008) 441.
[11]P.C. Okafor, M.E. Ikpi, I.E. Uwah, E.E. Ebenso, U.J. Ekpeand S.A. Umoren, Corros. Sci.50(2008) 2310.
[12]K.M. Ismail, Electrochim. Acta.52(2007) 7811.
[13]M. Lebrini, F. Robert and C. Roos, Int. J. Electrochem.Sci.5(2010) 1698.
[14]L. Afia, R. Salghi, L. Bammou, L. Bazzi, B. Hammoutiand L. Bazzi,Acta Metall. Sin. (Eng. Lett.).25(2012) 10.
[15]N. Lahhit, A. Bouyanzer, J.M. Desjobert, B. Hammouti,R. Salghi, J. Costa, C. Jama, F. Bentiss and L. Majidi, Portug.Electrochim. Acta29(2011) 127.
[16] K.P.Vinod kumar, M. Sangara Narayana Pillai and G. Rexin Thusnavis, J. Mater. Sci. Technol.27(2011) 1143.
[17] E.E. Oguzie, Corros. Sci.50(2008) 2993.
[18]R.S. Goncalves and LD. Mello, Corros. Sci.43(2001) 457.
[19]M.A. Amin, S.S.A. El-Sherbini and R.S. Bayoumy,Electrochim. Acta.52(2007) 3588.
[20] G. Moretti, F. Guidi and G. Grion, Corros. Sci.46(2004) 387.
[21] T. Fallavena, M. Antonow and R.S. Goncalves, Appl. Surf.Sci.253(2006) 566.
[22] A. Bouyanzer, B. Hammouti and L. Majidi, Mater. Lett. 60(2006) 2840.
[23]D.Q. Zhang, Q.R. Cai, L.X. Gao and K.Y. Lee, Corros.Sci.50(2008) 3615.
[24]F.S. de Souza and A. Spinelli, Corros. Sci.52(2009) 642.
[25] S.K. Arora and U.N. Joshi, Starch-Starke34 (1985) 109.
[26]P. Brindha, K. Sasikala and K. Purushoth, Ethnobotany 3(1977) 84.
[27]J.B. Harbone, Phytochemical Methods: A: Guide to ModernTechnique of Plant Analysis, 3rd Ed., Chapman and Hall, London,1988, p.1.
[28] A.K. Satapathy, G. Gunasekaran, S.C. Sahoo, K. Amit and P.V. Rodrigues,Corros. Sci.51(2009) 2848.
[29]M.A. Sathiq, A.J.A. Nasser and P.M. Sirajudeen, E-J.Chem.8(2011) 621.
[30]A. Jamal Abdul Nasser and M. Anwar Sathiq, Int. J. Eng.Sci. Technol.2(2010) 6417.
[31]Y.M. Tang, X.Y. Yang, W.Z. Yang, R. Wan, Y. Zhong and X.S. Yin, Corros. Sci.52(2010) 1801.
[32]M. Behpour, S.M. Ghoreish, N. Soltani and M.Salavati-Niasari, Corros. Sci.51(2009) 1073.
[33]A.Y. Musa, A.A.H. Kadhum, A.B. Mohamad and M.S. Takriff,Corros. Sci.52(2010) 3331.
[34]A.Y. El-Etre, J. Colloid. Int. Sci.314(2007)578.
[35]Y. Tang, X. Yang, W. Yang, R. Wan, Y. Chen and X. Yin,Corros. Sci.52(2010) 1801.
[36]W.A.W. Elyn Amira, A.A. Rahim, H. Osman, K. Awang and P. Bothiraja, Int. J. Electrochem. Sci.6(2011) 2998.
[37]M. Lebrini, F. Robert, P.A. Blandinieres and C. Roos,Curr. Appl. Phys.11(2011) 714.
[38]I. Naqvi, A.R. Saleemi and S. Naveed, Int. J.Electrochem. Sci.6(2011) 146.
[39]N.O. Obi-Egbedi and I.B. Obot, Arabian J. Chem.5(2010) 121.
[40]E.A. Noor and Aisha H. Al-Moubaraki, Mater. Chem. Phys.110(2008) 145.
[41]R. Saratha, S.V. Priya and P. Thilagavathy, E-J. Chem. 6(2009) 785.
[42]A.S. Fouda, A.A. Al-Sarawy and E.E. El-Katori,Desalination201(2006) 1.
[43]G.E. Badr, Corros. Sci.51(2009) 2529.
[44]M.M. Solomon, S.A. Umoren, I.I. Udosoro and A.P. Udoh,Corros. Sci.52(2010) 1317.
[45]G. Avci, Colloids Surfaces. A: Physicochem. Eng.Aspects.317(2008) 730.
[46]N. Gunavathy and S.C. Murugavel,E-J. Chem.9(2012) 487.
[47]U.M. Eduok, S.A. Umoren and A.P. Udoh, Arabian J. Chem.5(2012) 325.
[48]X.H. Li, S.D. Deng and H. Fu, Corros. Sci.62 (2012) 163.
[49]X.H. Li, S.D. Deng and H. Fu, Prog. Org. Coat.67(2010) 420.
[50]Y. Abboudi, B. Hammouti, A. Abourrichel, B. Ihssanel,A. Bennamarl, M. Charroufi and S.S. Al-Deyab, Int. J. Electrochem.Sci.7(2012) 2543.
[51] Y. Abboud, B. Hammouti, A. Abourriche, A. Bennamara and H. Hannache, Res. Chem.Intermed.38(2012) 1591.
[52] X.H. Li, S.D. Deng, H. Fu and T. Li, Corros. Sci.54(2009) 4089.
/
| 〈 |
|
〉 |
WeChat