Elastic and Thermo-physical Properties of Stannite-type Cu2ZnSnS4 and Cu2ZnSnSe4 from First-principles Calculations

  • Xiancong HE ,
  • Jinhong PI ,
  • Yuming DAI ,
  • Xiaoquan LI
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  • Department of Materials Science and Engineering, Nanjing Institute of Technology, Nanjing 211167, China

Received date: 2012-12-10

  Revised date: 2013-02-26

  Online published: 2013-05-06

Supported by

National Natural Science Foundation of China (No. 51075197).

Abstract

Cu2ZnSnS4 (CZTS) and Cu2ZnSnSe4 (CZTSe) with optimum band gaps about 1.5 eV are important absorbers for solar cells. The elastic constants and the thermo-physical properties of the stannite-type CZTS and CZTSe are calculated by using density-functional theory (DFT) and the quasi-harmonic Debye model. The bonding strength along the [100] and [010] directions is the same to that along the [001] direction and the shear elastic properties of the {001} plane are anisotropic for CZTS and CZTSe. Both compounds exhibit ductile behavior due to their high ratio of bulk modulus to shear modulus (K/G). The values of thermal capacity are close to 200 J/(mol·K) at above 300 K, and the thermal expansion coefficients decrease with increasing pressure at same temperature. The entropy is variable by power-exponent, and the internal energy is almost linear with increasing temperature for CZTS and CZTSe. The Gibbs energy of CZTS is lower than that of CZTSe under same temperature and pressure. The Debye temperatures are 297 and 232 K, and Gruneisen parameters are 2.36 and 2.37 for CZTS and CZTSe at 300 K, respectively.

Cite this article

Xiancong HE , Jinhong PI , Yuming DAI , Xiaoquan LI . Elastic and Thermo-physical Properties of Stannite-type Cu2ZnSnS4 and Cu2ZnSnSe4 from First-principles Calculations[J]. Acta Metallurgica Sinica (English Letters), 2013 , 26(3) : 285 -292 . DOI: 10.1007/s40195-012-0248-4

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