EFFECTS OF HDDR PROCESS ON STRUCTURE AND MAGNETIC PROPERTIES OF Nd(Fe,Ti)_(12)N_δ PREPARED BY MECHANICAL ALLOYING

Abstract

Abstract: The effects of the hydrogenation-disproportionation-desorption-recombination (HDDR) process on the structure and the magnetic properties of the mechanical alloying (MA) prepared Nd8Fe84 Ti8 alloy and its nitride counterpart have been studied in detail. It has been found that Nd(Fe, Ti)12Hδ is formed in the temperature range from 300 to 550°℃. The disproportionation is ready to start at 550°℃ and is complete at 960°℃.The desorption and the recombination are almost synchronized. The phase of Nd(Fe,Ti)7 is formed at 750°℃ during the HDDR treatment. With increasing temperature of HDDR process, the metastable structure of TbCu7 type is gradually transformed into the structure of ThMn12 type. The intrinsic coercivity and the maximum magnetic energy product increase with increasing temperature of HDDR process.

Key words: Nd(Fe, Ti)_(12)N_δ compound, magnetic property, hydrogenation

B.Z Cui; X. K. Sun; X.G. Zhao;W.Liu;Q.F. Xiao;T. Zhao; Z.D. Zhang andY.C.Sui(Institute of Metal Research, The Chinese Academy of Sciences, Shenyang 110015, China). EFFECTS OF HDDR PROCESS ON STRUCTURE AND MAGNETIC PROPERTIES OF Nd(Fe,Ti)_(12)N_δ PREPARED BY MECHANICAL ALLOYING[J]. Acta Metallurgica Sinica (English Letters), 1998, 11(1): 68-78.

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EFFECTS OF HDDR PROCESS ON STRUCTURE AND MAGNETIC PROPERTIES OF Nd(Fe,Ti)_(12)N_δ PREPARED BY MECHANICAL ALLOYING

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