Abstract: The electrochemical behaviour, including free corrosion potential, free corrosion current density and polarization curve, of various thermal history zones on the weldment was measured in this paper. The weldment consisted of matrix, tempering zone. incomplete normalized zone, normalized zone, overtemperature zone, fusion line zone and weld metal zone. The electrochemical behaviour of the ferrite, pearlite and mixed structure in various zones have successfully measured. The results showed that there was a difference of free corrosion potential which is smaller than ca. 200mV between various zones and about 20-150mV potential difference between ferrite and pearlite in every zone. The free cormsion potential of fusion line zone was the most negative between various zones. The free corrosion potential of pearlite was some dozens mV more negative than ferrite. The corrosion course of various zones and of different phase structures on the weldment and their effect on corrosion attack of weldment were discussed.

Key words: weldment, phase electrochemistry, galvanic effect, thermal history zone